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Draft · Membranes

Does free chlorine damage a membrane?

The short answer: yes, and irreversibly. Membranes have a low tolerance to chlorine and the damage cannot be undone by cleaning.

The tolerance limit is low

Reverse osmosis membranes have a notably low tolerance to chlorine. Where free chlorine in the water exceeds 1 ppm, the membrane is damaged.

That damage differs from fouling in one important respect: fouling can be removed by cleaning, chlorine damage cannot. A damaged membrane has to be replaced.

How you notice the damage

With chlorine damage the membrane loses its ability to retain. The result appears as a simultaneous rise in production flow and in permeate conductivity — the system produces more water, but the water is of lower quality.

A rising flow may look positive at first; read without conductivity alongside it, this symptom is easily missed.

The precaution is taken ahead of the membrane

Chlorine is already present in mains water for disinfection purposes; the problem is not that chlorine exists but that it reaches the membrane. Free chlorine must therefore always be removed from the water ahead of the membrane.

Skipping that stage in the pretreatment arrangement means leaving the most expensive consumable unprotected.

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